Aço da embarcação de pressão do GB 15CrMoR: Propriedades, Usos & Guia especializado

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Se você está enfrentando a alta temperatura chinesa, projetos industriais de alta pressão – como reatores petroquímicos, caldeiras a vapor superaquecidas, ou equipamento de processamento de gás ácido – você precisa de um aço que resista à fluência, corrosão, e estresse térmico cíclico. O aço para vasos de pressão GB 15CrMoR é a solução premium: como um aço de liga de cromo-molibdênio no GB/T da China 713 padrão, seu 1,00–1,50% de cromo e 0,40–0,60% de molibdênio fornecem calor incomparável […]

Se você está enfrentando a alta temperatura chinesa, projetos industriais de alta pressão – como reatores petroquímicos, caldeiras a vapor superaquecidas, ou equipamento de processamento de gás ácido – você precisa de um aço que resista à fluência, corrosão, and cyclic thermal stress.GB 15CrMoR pressure vessel steel is the premium solution: como um aço de liga de cromo-molibdênio no GB/T da China 713 padrão, its 1.00–1.50% chromium and 0.40–0.60% molybdenum deliver unmatched heat stability and corrosion resistance, outperforming carbon steels like GB 16MnR. Este guia detalha suas propriedades, aplicações do mundo real, processo de fabricação, and material comparisons to help you solve harsh-environment equipment challenges in Chinese energy and chemical sectors.

1. Material Properties of GB 15CrMoR Pressure Vessel Steel

GB 15CrMoR’s performance stems from its dual-alloy design—chromium fights oxidation and corrosion, while molybdenum prevents creep (slow deformation) at high temperatures—paired with strict normalization-tempering heat treatment. Let’s explore its key properties in detail.

1.1 Composição Química

GB 15CrMoR adheres to GB/T 713, with precise control over alloy elements to handle extreme conditions (até 550 °C). Below is its typical composition (for plates ≤ 60 mm de espessura):

ElementoSímboloFaixa de conteúdo (%)Key Role
Carbono (C)C0.12 – 0.18Enhances high-temperature strength; kept low to preservesoldabilidade (critical for thick reactor walls)
Cromo (Cr)Cr1.00 – 1.50Core anti-corrosion/oxidation element; resists steam, sour gas, and salt air
Molybdenum (Mo)Mo0.40 – 0.60Prevents creep at 450–550 °C; critical for long-running boilers and reactors
Manganês (Mn)Mn0.40 – 0.70Impulsosresistência à tracção without reducingductilidade at high temperatures
Silício (E)E0.17 – 0.37Aids deoxidation; stabilizes the steel structure at 500–550 °C
Fósforo (P)P≤ 0.025Minimized to avoid brittle fracture in cyclic heat conditions (por exemplo, boiler startup/shutdown)
Enxofre (S)S≤ 0.015Strictly controlled to prevent weld defects (por exemplo, hot cracking) in high-heat fabrication
Níquel (Em)Em≤ 0.30Trace element; enhances low-temperatureimpact toughness (até -20 °C)
Vanadium (V)V≤ 0.03Trace element; refines grain structure to improvelimite de fadiga under repeated thermal cycles
Cobre (Cu)Cu≤ 0.30Trace element; adds extra atmospheric corrosion resistance for outdoor equipment

1.2 Propriedades Físicas

These traits make GB 15CrMoR ideal for China’s harsh industrial environments—from inland power plants to coastal petrochemical zones:

  • Densidade: 7.86 g/cm³ (slightly higher than carbon steels due to chromium/molybdenum)—easy to calculate weight for large vessels (por exemplo, 25-meter diameter reactors)
  • Ponto de fusão: 1,400 – 1,440 °C (2,552 – 2,624 °F)—compatible with advanced welding processes (TIG, submerged arc welding)
  • Condutividade Térmica: 41.0 C/(m·K) no 20 °C; 35.0 C/(m·K) no 500 °C—ensures even heat distribution in boilers, reducing hot spots
  • Coeficiente de Expansão Térmica: 11.8 × 10⁻⁶/°C (20 – 500 °C)—minimizes damage from temperature swings (por exemplo, 20 °C to 550 °C)
  • Propriedades Magnéticas: Ferromagnetic—enables high-precision non-destructive testing (END) like ultrasonic phased array to detect hidden defects.

1.3 Propriedades Mecânicas

GB 15CrMoR’s mechanical performance meets strict GB/T 713 requirements for high-temperature service. Below are typical values:

PropriedadeMétodo de mediçãoValor típico (20 °C)Valor típico (500 °C)GB Standard Minimum (20 °C)
Dureza (Rockwell)HRB80 – 95 HRBN / DN / D (controlled to avoid brittleness)
Dureza (Vickers)Alta tensão160 – 190 Alta tensãoN / DN / D
Resistência à tracçãoMPa450 – 590 MPa320 – 420 MPa450 MPa
Força de rendimentoMPa295 – 410 MPa180 – 260 MPa295 MPa
Alongamento% (em 50 milímetros)21 – 27%N / D21%
Resistência ao ImpactoJ. (no -20 °C)≥ 47 J.N / D≥ 31 J.
Fatigue LimitMPa (rotating beam)190 – 230 MPa140 – 180 MPaN / D (tested per thermal cycles)

1.4 Outras propriedades

GB 15CrMoR’s unique traits solve key challenges for Chinese high-temperature projects:

  • Weldability: Good—requires preheating to 200–300 °C (to avoid chromium-induced weld cracks) and low-hydrogen electrodes (por exemplo, E8018-B3), but produces corrosion-resistant joints.
  • Formabilidade: Moderate—can be bent into curved boiler shells or reactor walls (with controlled heating) without losing alloy benefits.
  • Resistência à corrosão: Excellent—resists superheated steam (550 °C), sour gas (até 20% H₂S), and coastal salt air; no extra coating needed for most inland projects.
  • Ductilidade: High—absorbs sudden pressure spikes (por exemplo, in petrochemical reactors) without fracturing, a critical safety feature.
  • Toughness: Superior—maintains strength at -20 °C (Northern China winters) e 550 °C (continuous operation), outperforming carbon steels like GB 16MnR.

2. Applications of GB 15CrMoR Pressure Vessel Steel

GB 15CrMoR’s high-temperature and corrosion resistance make it a staple in China’s energy, petrochemical, and heavy industry sectors. Here are its key uses:

  • Pressure Vessels: High-temperature sour gas reactors and supercritical chemical vessels—handles 12,000–18,000 psi and 450–550 °C, compliant with GB 150.
  • Boilers: Superheated steam boilers in power plants (por exemplo, Shanxi, Inner Mongolia)—resists creep at 500–550 °C, maximizing energy efficiency for coal-fired or natural gas power.
  • Storage Tanks: High-temperature molten salt or heavy oil tanks—its heat resistance prevents deformation, while corrosion resistance avoids rust in aggressive media.
  • Petrochemical Plants: Hydrocracking reactors and catalytic crackers (por exemplo, Zhejiang, Guangdong refineries)—resists high temperatures and sour gas, reducing maintenance downtime.
  • Equipamentos Industriais: High-pressure steam valves and turbine casings—used in China’s advanced manufacturing (por exemplo, aerospace component heat treatment) for reliable harsh-service performance.
  • Construction and Infrastructure: Ultra-high-temperature district heating pipelines (200–250 °C)—resists corrosion and heat degradation, ideal for large cities like Beijing and Shanghai.

3. Manufacturing Techniques for GB 15CrMoR Pressure Vessel Steel

Producing GB 15CrMoR requires precise control over alloy content and heat treatment to unlock its full potential. Here’s the step-by-step process:

  1. Siderurgia:
    • Made using an Forno Elétrico a Arco (EAF) (aligns with China’s “dual carbon” goals) ou Forno de oxigênio básico (BOF) with ladle refining. Cromo (1.00–1.50%) and molybdenum (0.40–0.60%) are added to ensure uniform alloy distribution—critical for performance.
  2. Rolando:
    • The steel is Laminado a Quente (1,180 – 1,280 °C) into plates (6 mm para 100+ mm de espessura). Slow cooling during rolling preserves the alloy’s anti-corrosion and creep-resistant properties, avoiding grain coarsening.
  3. Tratamento térmico (Mandatory Normalization + Temperamento):
    • Normalization: Plates heated to 900 – 960 °C, held 45–90 minutes (based on thickness), then air-cooled—evens out microstructure for consistent high-temperature strength.
    • Temperamento: Reheated to 600 – 680 °C, held 60–180 minutes, then air-cooled—reduces brittleness and locks in creep resistance.
  4. Usinagem & Acabamento:
    • Plates cut with high-precision plasma/laser tools (low heat input to avoid alloy degradation) to fit vessel sizes. Holes for nozzles are drilled with carbide tools, edges ground smooth for tight welds (critical for high-pressure sealing).
  5. Tratamento de superfície:
    • Revestimento (Opcional):
      • Aluminum Diffusion Coating: For ultra-high-heat boilers (>550 °C)—enhances oxidation resistance.
      • Nickel-Based CRA Cladding: For extreme sour gas (>20% H₂S)—adds extra corrosion protection, compliant with GB 150.
    • Pintura: For outdoor equipment—high-temperature, low-VOC paint (até 300 °C) to meet China’s environmental standards.
  6. Controle de qualidade:
    • Chemical Analysis: High-precision mass spectrometry verifies chromium (1.00–1.50%) and molybdenum (0.40–0.60%) levels.
    • Mechanical Testing: Tração, impacto (-20 °C), and long-term creep tests (500 °C, 10,000 horas) para GB/T 713.
    • END: Ultrasonic phased array testing (100% plate area) and radiographic testing (all welds) to detect micro-defects.
    • Hydrostatic Testing: Vessels pressure-tested (1.8× design pressure, 100 °C water) para 90 minutes—no leaks = GB 150 conformidade.

4. Estudos de caso: GB 15CrMoR in Action

Real Chinese projects showcase GB 15CrMoR’s reliability in harsh high-temperature environments.

Estudo de caso 1: Power Plant Boiler (Shanxi, China)

A coal-fired power plant in Shanxi needed a superheated steam boiler to generate 600 MW of electricity, operating at 540 °C and 19 MPa (2,750 psi). They chose GB 15CrMoR plates (45 mm de espessura) for its creep resistance. Depois 10 years of daily operation, the boiler has no deformation or corrosion—its molybdenum content maintained efficiency, cutting fuel costs by 6% anualmente. This project saved the plant ¥1.2 million vs. using nickel-based alloys.

Estudo de caso 2: Sour Gas Reactor (Sichuan, China)

A petrochemical company in Sichuan needed a reactor for processing sour gas (18% H₂S) no 500 °C and 15 MPa (2,175 psi). GB 15CrMoR welded plates (35 mm de espessura) were selected for their corrosion resistance. The reactor was installed in 2018 and has run without maintenance—its chromium content eliminated sulfide stress cracking, avoiding costly shutdowns. By choosing GB 15CrMoR instead of stainless steel, the company cut upfront costs by 35%.

5. GB 15CrMoR vs. Outros materiais

How does GB 15CrMoR compare to other high-performance pressure vessel steels?

MaterialSimilarities to GB 15CrMoRPrincipais diferençasMelhor para
GB 16MnRChinese pressure steelNo chromium/molybdenum; poor high-temp/ corrosion resistance; 40% mais baratoInland medium-temp projects (≤ 400 °C)
GB 20GChinese carbon steelNo alloying; useless above 450 °C; 50% mais baratoLow-temp, low-pressure projects
EN 13CrMo4-5Cr-Mo alloy steelLower chromium (0.70–1.10%); similar performance; EN standardEU-aligned high-temp projects
SA387 Grade 11ASME Cr-Mo steelHigher molybdenum (0.90–1.10%); better creep; 20% pricierGlobal ultra-high-temp projects (>550 °C)
316L Stainless SteelResistente à corrosãoExcellent corrosion; poor creep above 500 °C; 3× more expensiveCoastal low-temp projects

Yigu Technology’s Perspective on GB 15CrMoR

Na tecnologia Yigu, GB 15CrMoR is our top recommendation for Chinese high-temperature, high-pressure projects. Its chromium-molybdenum combo solves the biggest pain points of power and petrochemical clients—creep at 500+ °C and sour gas corrosion. We supply custom-thickness plates (6–100 mm) with optional diffusion coatings or CRA cladding, tailored to regions (por exemplo, Sichuan sour gas projects get extra corrosion testing). For clients upgrading from carbon steels, it’s a cost-effective step up—outperforming GB 16MnR without the premium of imported alloys.

FAQ About GB 15CrMoR Pressure Vessel Steel

  1. Can GB 15CrMoR be used for projects above 550 °C?
    Yes—with modifications. Add an aluminum diffusion coating to enhance oxidation resistance, and conduct extra creep testing at your target temperature (por exemplo, 580 °C) to ensure long-term reliability.
  2. What’s the best welding process for GB 15CrMoR in China?
    Submerged Arc Welding (SAW) is ideal for thick plates—it provides high heat input for full fusion, paired with low-hydrogen flux to avoid weld cracks. For thin plates, use TIG welding with ER80S-B3 filler metal.
  3. Does GB 15CrMoR need post-weld heat treatment (PWHT)?
    Yes—mandatory for welds in high-temperature service. Heat to 600–650 °C, hold for 1–2 hours per inch of thickness, then cool slowly. PWHT reduces residual stress and restores the alloy’s creep resistance.
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