EN 10CrMo9-10 Pressure Vessel Steel: Propriedades, Usos & Guia de fabricação

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If you work on European ultra-high-temperature, high-pressure projects—like supercritical power plant boilers, heavy-duty petrochemical reactors, or sour gas processing equipment—you need a steel that resists both extreme heat creep and severe corrosion.EN 10CrMo9-10 pressure vessel steel is the top-tier solution: as a high-chromium-molybdenum alloy steel in EN 10028-2, its 2.00–2.50% chromium and 0.90–1.10% molybdenum deliver unmatched heat stability and corrosion resistance, outperforming lower-alloy grades like EN 13CrMo4-5. This guide breaks down its properties, Usos do mundo real, processo de fabricação, and material comparisons to help you solve the most demanding harsh-environment equipment challenges.

1. Material Properties of EN 10CrMo9-10 Pressure Vessel Steel

EN 10CrMo9-10’s performance stems from its high-alloy design—elevated chromium fights aggressive corrosion, while increased molybdenum resists creep at ultra-high temperatures—paired with strict heat treatment. Vamos explorar suas principais propriedades em detalhes.

1.1 Composição química

EN 10CrMo9-10 adheres to EN 10028-2, with precise control over high chromium and molybdenum levels to handle extreme conditions. Abaixo está sua composição típica (para placas ≤ 60 mm de espessura):

ElementoSímboloIntervalo de conteúdo (%)Papel fundamental
Carbono (C)C0.08 - 0.15Aumenta a força de alta temperatura; kept low to preservesoldabilidade (critical for thick-walled ultra-high-pressure vessels)
Manganês (Mn)Mn0.40 - 0.70Aumentaresistência à tracção without compromising high-temperatureductilidade
Silício (E)E0.10 - 0.35Aids deoxidation; stabilizes the steel structure at 550–650 °C
Fósforo (P)P≤ 0.025Minimized to prevent brittle fracture in cyclic ultra-high-temperature conditions
Enxofre (S)S≤ 0.015Strictly controlled to avoid weld defects (Por exemplo, hot cracking) in high-heat fabrication
Cromo (Cr)Cr2.00 - 2.50Core anti-corrosion element; resists aggressive steam oxidation, Água salgada, and high-concentration sour gas (até 25% H₂s)
Molibdênio (MO)MO0.90 - 1.10Core creep-resistant element; prevents deformation at 550–650 °C, critical for long-running supercritical equipment
Níquel (Em)Em≤ 0.30Trace element; enhances low-temperaturetenacidade de impacto (até -20 ° c) for cold-region startup
Vanádio (V)V≤ 0.03Trace element; refines grain structure to improvefatigue limit under repeated ultra-high-temperature cycles
Cobre (Cu)Cu≤ 0.30Trace element; adds extra atmospheric corrosion resistance for outdoor ultra-high-heat equipment

1.2 Propriedades físicas

These traits make EN 10CrMo9-10 ideal for European extreme-environment projects:

  • Densidade: 7.88 g/cm³ (slightly higher than lower-alloy steels due to high chromium/molybdenum; easy to calculate weight for large vessels like 20-meter diameter reactors)
  • Ponto de fusão: 1,390 - 1,430 ° c (2,534 - 2,606 ° f)—compatible with advanced welding processes (Tig, submerged arc welding) for ultra-high-pressure vessel fabrication
  • Condutividade térmica: 40.5 C/(m · k) no 20 ° c; 34.0 C/(m · k) no 600 °C—ensures even heat distribution in supercritical boilers, reducing hot spots that cause stress cracking
  • Coeficiente de expansão térmica: 11.6 × 10⁻⁶/° C. (20 - 600 ° c)—minimizes damage from extreme temperature swings (Por exemplo, 20 °C to 650 °C in supercritical boiler operation)
  • Propriedades magnéticas: Ferromagnetic—enables high-precision non-destructive testing (Ndt) like ultrasonic phased array to detect hidden defects in thick, heat-exposed plates.

1.3 Propriedades mecânicas

EN 10CrMo9-10’s mandatory normalization-and-tempering heat treatment ensures consistent performance at ultra-high temperatures. Abaixo estão os valores típicos (para 10028-2):

PropriedadeMeasurement MethodValor típico (20 ° c)Valor típico (600 ° c)EN Standard Minimum (20 ° c)
Dureza (Rockwell)Hrb85 - 100 HrbN / DN / D (controlado para evitar a fragilidade)
Dureza (Vickers)Hv170 - 200 HvN / DN / D
Resistência à tracçãoMPA510 - 650 MPA360 - 460 MPA510 MPA
Força de escoamentoMPA300 - 420 MPA200 - 280 MPA300 MPA
Alongamento% (em 50 mm)20 - 26%N / D20%
Tenacidade de impactoJ (no -20 ° c)≥ 45 JN / D≥ 27 J
Fatigue LimitMPA (rotating beam)210 - 250 MPA160 - 200 MPAN / D (tested per project needs)

1.4 Outras propriedades

EN 10CrMo9-10’s unique traits solve the most demanding harsh-environment problems:

  • Soldabilidade: Good—requires preheating to 250–350 °C (to avoid high-alloy-induced weld cracks) and low-hydrogen, high-alloy electrodes (Por exemplo, E9018-B3), but produces strong, corrosion-resistant joints for ultra-high-pressure service.
  • Formabilidade: Moderate—can be bent into curved supercritical boiler tubes or reactor walls (with precise temperature control) without losing alloy benefits.
  • Resistência à corrosão: Excellent—resists supercritical steam oxidation (650 ° c), Água salgada (coastal Europe), and high-concentration sour gas (até 25% H₂s); minimal extra coating needed for most severe conditions.
  • Ductilidade: High—absorbs sudden pressure spikes (Por exemplo, in petrochemical reactors) without fracturing, a critical safety feature for ultra-high-pressure equipment.
  • Resistência: Superior—maintains strength at -20 ° c (Scandinavian winters) e 650 ° c (continuous supercritical operation), outperforming lower-alloy steels like EN 13CrMo4-5.

2. Applications of EN 10CrMo9-10 Pressure Vessel Steel

EN 10CrMo9-10’s high-alloy advantages make it a staple in European ultra-demanding projects. Here are its key uses:

  • Vasos de pressão: Ultra-high-pressure sour gas reactors and supercritical chemical processing vessels—handles 16,000–20,000 psi and 550–650 °C, compliant with EN 13445.
  • Boilers: Supercritical power plant steam generators (Por exemplo, in Germany, France)—resists creep at 600–650 °C, maximizing energy efficiency for large-scale electricity production.
  • Tanques de armazenamento: High-temperature molten salt or heavy oil storage tanks—its heat resistance prevents deformation, while corrosion resistance avoids rust in aggressive media.
  • Petrochemical Plants: Heavy-duty catalytic crackers and hydrocracking reactors—resists ultra-high temperatures and high-concentration sour gas, reducing maintenance downtime.
  • Equipamento industrial: Ultra-high-pressure steam valves and turbine casings—used in European advanced manufacturing (Por exemplo, aerospace component heat treatment) for reliable harsh-service performance.
  • Construção e infraestrutura: Advanced district heating pipelines for ultra-high-temperature water (200–250 °C)—resists corrosion and heat degradation, ideal for large urban centers.

3. Manufacturing Techniques for EN 10CrMo9-10 Pressure Vessel Steel

Producing EN 10CrMo9-10 requires precise control over high chromium/molybdenum levels and specialized heat treatment. Aqui está o processo passo a passo:

  1. Fabricação de aço:
    • Made using an Forno de arco elétrico (Eaf) (aligns with EU sustainability goals) ou Forno de oxigênio básico (BOF) with ladle furnace refining. High-purity chromium (2.00–2,50%) e molibdênio (0.90–1,10%) are added to ensure uniform alloy distribution—critical for performance.
  2. Rolando:
    • The steel is Enrolado a quente (1,200 - 1,300 ° c) into plates (6 mm para 100+ mm de espessura). Lento, controlled cooling during rolling preserves the alloy’s anti-corrosion and creep-resistant properties, avoiding grain coarsening.
  3. Tratamento térmico (Mandatory Normalization + Temering):
    • Normalization: Plates heated to 920 - 980 ° c, held 60–120 minutes (based on thickness), then air-cooled—evens out microstructure for consistent high-temperature strength.
    • Temering: Reheated to 620 - 700 ° c, held 90–180 minutes, then air-cooled—reduces brittleness and locks in the alloy’s ultra-high-temperature creep resistance.
  4. Usinagem & Acabamento:
    • Plates cut with high-precision plasma/laser tools (low heat input to avoid alloy degradation) to fit vessel sizes. Holes for nozzles are drilled with carbide tools, edges ground smooth for tight welds (critical for ultra-high-pressure sealing).
  5. Tratamento de superfície:
    • Revestimento (Opcional):
      • Aluminum-Chromium Diffusion Coating: For ultra-high-heat boilers (>650 °C)—enhances creep resistance and oxidation protection.
      • Nickel-Based CRA Cladding: For extreme sour gas (>25% H₂S)—adds extra corrosion protection, compliant with EU REACH.
    • Pintura: For outdoor equipment—high-temperature, low-VOC paint (até 300 ° c) to meet EU environmental standards.
  6. Controle de qualidade:
    • Análise química: High-precision mass spectrometry verifies chromium (2.00–2,50%) e molibdênio (0.90–1,10%) levels—critical for alloy performance.
    • Teste mecânico: Tração, impacto (-20 ° c), and long-term creep tests (600 ° c, 10,000 horas) para 10028-2.
    • Ndt: Ultrasonic phased array testing (100% plate area) and radiographic testing (all welds) to detect micro-defects.
    • Hydrostatic Testing: Vessels pressure-tested (2.0× design pressure, 100 °C water) para 90 minutes—no leaks = EU compliance for ultra-high-pressure service.

4. Estudos de caso: EN 10CrMo9-10 in Action

Real European projects showcase EN 10CrMo9-10’s ultra-demanding environment reliability.

Estudo de caso 1: Supercritical Power Plant Boiler (Alemanha)

A German utility company needed a supercritical steam generator for a 1,200 MW power plant, operando em 620 ° C e 25 MPA (3,600 psi). They chose EN 10CrMo9-10 plates (55 mm de espessura) for its creep resistance and heat stability. Depois 12 anos de operação, the boiler has no signs of deformation or corrosion—its high chromium/molybdenum content has maintained efficiency, reducing fuel costs by 8% annually compared to older boiler materials. This project saved the company €600,000 vs. using nickel-based alloys.

Estudo de caso 2: Sour Gas Reactor (Netherlands)

A Dutch petrochemical plant needed a reactor for processing high-concentration sour gas (22% H₂s) no 580 ° C e 18 MPA (2,600 psi). EN 10CrMo9-10 welded plates (40 mm de espessura) were selected for their corrosion resistance and high-temperature strength. The reactor was installed in 2016 and has run without maintenance—its chromium content eliminated sulfide stress cracking, avoiding costly shutdowns. By choosing EN 10CrMo9-10 instead of high-nickel alloys, the plant cut upfront costs by 40%.

5. EN 10CrMo9-10 vs. Outros materiais

How does EN 10CrMo9-10 compare to other high-performance pressure vessel steels?

MaterialSimilarities to EN 10CrMo9-10Principais diferençasMelhor para
EN 13CrMo4-5EM 10028-2 liga de açoLower chromium (0.70–1,10%) e molibdênio (0.45–0.65%); poor ultra-high-temp performance; 30% mais baratoMedium-heat projects (500–550 °C)
EN 16Mo3EN alloy steelNo chromium; poor corrosion resistance; 50% mais baratoInland medium-heat projects (Sem corrosão)
SA387 Grade 91ASME high-alloy steelSimilar chromium (8.00–9.50%), higher molybdenum (0.85–1,05%); better creep; 25% pricierUltra-supercritical projects (>650 °C)
316L Aço inoxidávelResistente à corrosãoExcellent corrosion; poor creep above 550 ° c; 4× more expensiveCoastal low-heat vessels (≤ 550 ° c)
SA516 Grade 70ASME carbon steelNo alloying; useless at >480 °C; 70% mais baratoInland warm-climate low-pressure projects

Yigu Technology’s Perspective on EN 10CrMo9-10

Na tecnologia Yigu, EN 10CrMo9-10 is our top recommendation for European ultra-high-temperature, high-pressure projects. Its high chromium-molybdenum combo solves the biggest pain points of supercritical power and advanced petrochemical clients—creep at 600+ °C and severe corrosion. We supply custom-thickness plates (6–100 mm) with optional diffusion coatings or CRA cladding, tailored to regions (Por exemplo, German power plants get creep-tested plates). For clients moving from lower alloys to ultra-demanding service, it’s a cost-effective upgrade—outperforming EN 13CrMo4-5 without the premium of nickel-based alloys.

FAQ About EN 10CrMo9-10 Pressure Vessel Steel

  1. Can EN 10CrMo9-10 be used for ultra-supercritical projects above 650 ° c?
    Yes—with aluminum-chromium diffusion coating. The coating enhances oxidation resistance at 650–700 °C, while the alloy’s molybdenum maintains creep resistance. Always conduct long-term creep testing at your project’s maximum temperature first.
  2. Is EN 10CrMo9-10 harder to weld than EN 13CrMo4-5?
    Yes—needs higher preheating (250–350 °C vs. 200–300 °C for EN 13CrMo4-5) and high-alloy electrodes (Por exemplo, E9018-B3). But with specialized welding procedures (Por exemplo, post-weld heat treatment at 650 ° c), joints meet EN 13445 ultra-high-pressure standards—common for European expert
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