If you’re tackling European projects that demand resistance to both high temperatures and corrosion—like coastal power plant boilers, offshore petrochemical reactors, or sour gas storage tanks—EN 13CrMo4-5 pressure vessel steel is your most reliable choice. As a chromium-molybdenum alloy steel in the EN 10028-2 standard, it combines 0.70–1.10% chromium (untuk perlindungan kakisan) and 0.45–0.65% molybdenum (untuk rintangan haba) to outperform non-alloyed grades like EN P355GH. This guide breaks down its properties, Aplikasi dunia nyata, proses pembuatan, and material comparisons to help you solve harsh-environment equipment challenges.
1. Material Properties of EN 13CrMo4-5 Pressure Vessel Steel
EN 13CrMo4-5’s dual-alloy design is what makes it stand out: chromium fights rust and oxidation, while molybdenum prevents slow deformation (merayap) pada suhu tinggi. Mari kita meneroka sifat utamanya secara terperinci.
1.1 Komposisi kimia
EN 13CrMo4-5 follows strict EN 10028-2 piawaian, with precise control over alloy elements to ensure performance in harsh conditions. Berikut adalah komposisi biasa (untuk plat ≤ 60 mm tebal):
Elemen | Simbol | Julat Kandungan (%) | Peranan utama |
---|---|---|---|
Karbon (C) | C | 0.12 - 0.18 | Boosts strength; kept low to preservekebolehkalasan (critical for thick vessel walls) |
Mangan (Mn) | Mn | 0.40 - 0.70 | Meningkatkankekuatan tegangan without reducing high-temperatureKemuluran |
Silikon (Dan) | Dan | 0.10 - 0.35 | Helps remove oxygen during steelmaking; stabilizes the structure at 500–600 °C |
Fosforus (P) | P | ≤ 0.025 | Minimized to avoid brittle fracture in cold or cyclic heat (Mis., winter boiler startup) |
Sulfur (S) | S | ≤ 0.015 | Strictly controlled to prevent weld defects (like hot cracking) in humid coastal air |
Chromium (Cr) | Cr | 0.70 - 1.10 | Core anti-corrosion element; Menentang air masin, steam oxidation, and mild sour gas |
Molybdenum (Mo) | Mo | 0.45 - 0.65 | Prevents creep deformation at high temperatures (500-600 ° C.), critical for long-running equipment |
Nikel (Dalam) | Dalam | ≤ 0.30 | Trace element; improves low-temperaturekesan ketangguhan (turun ke -20 ° C.) |
Vanadium (V) | V | ≤ 0.03 | Trace element; refines grain structure to boostfatigue limit under repeated heat cycles |
Tembaga (Cu) | Cu | ≤ 0.30 | Trace element; adds extra resistance to atmospheric corrosion for outdoor tanks |
1.2 Sifat fizikal
These traits make EN 13CrMo4-5 ideal for European environments like coastal regions or industrial zones:
- Ketumpatan: 7.87 g/cm³ (slightly higher than non-alloy steels due to chromium/molybdenum)—easy to calculate weight for large vessels (Mis., 15-meter diameter reactors)
- Titik lebur: 1,400 - 1,440 ° C. (2,552 - 2,624 ° f)—works with standard welding methods (TIG, Melihat) used in European fabrication shops
- Kekonduksian terma: 42.0 W/(m · k) pada 20 ° C.; 36.5 W/(m · k) pada 550 °C—ensures even heat spread in boilers, reducing hot spots that cause stress
- Pekali pengembangan haba: 11.7 × 10⁻⁶/° C. (20 - 550 ° C.)—minimizes damage from temperature swings (Mis., 20 °C to 550 °C in boiler operation)
- Sifat magnet: Ferromagnetic—lets you use non-destructive testing (Ndt) like magnetic particle inspection to find hidden weld defects.
1.3 Sifat mekanikal
EN 13CrMo4-5’s mandatory heat treatment (normalization + pembiakan) ensures consistent performance. Di bawah adalah nilai biasa (untuk 10028-2):
Harta | Measurement Method | Nilai tipikal (20 ° C.) | Nilai tipikal (550 ° C.) | EN Standard Minimum (20 ° C.) |
---|---|---|---|---|
Kekerasan (Rockwell) | HRB | 80 - 95 HRB | N/a | N/a (dikawal untuk mengelakkan keburukan) |
Kekerasan (Vickers) | Hv | 160 - 190 Hv | N/a | N/a |
Kekuatan tegangan | MPA | 480 - 620 MPA | 340 - 440 MPA | 480 MPA |
Kekuatan hasil | MPA | 290 - 410 MPA | 190 - 260 MPA | 290 MPA |
Pemanjangan | % (dalam 50 mm) | 22 - 28% | N/a | 22% |
Kesan ketangguhan | J (pada -20 ° C.) | ≥ 45 J | N/a | ≥ 27 J |
Fatigue Limit | MPA (rotating beam) | 200 - 240 MPA | 150 - 190 MPA | N/a (tested per project needs) |
1.4 Sifat lain
EN 13CrMo4-5’s unique traits solve common harsh-environment problems:
- Kebolehkalasan: Good—needs preheating to 200–300 °C (to avoid chromium-induced cracks) and low-hydrogen electrodes (Mis., E8018-B3), but produces strong, Kimpalan tahan kakisan.
- Kebolehbaburan: Moderate—can be bent into curved boiler shells or reactor walls (with controlled heating) without losing alloy benefits.
- Rintangan kakisan: Excellent—resists saltwater (coastal Europe), steam oxidation (dandang), and mild sour gas (hingga 15% H₂s) without extra coatings.
- Kemuluran: High—absorbs sudden pressure spikes (Mis., in petrochemical reactors) tanpa pecah, a key safety feature.
- Ketangguhan: Reliable—works at -20 ° C. (Scandinavian winters) dan 600 ° C. (continuous boiler use), outperforming single-alloy steels like EN 16Mo3.
2. Applications of EN 13CrMo4-5 Pressure Vessel Steel
EN 13CrMo4-5’s dual resistance (haba + kakisan) makes it a top choice for European projects in harsh environments. Here are its key uses:
- Kapal tekanan: Offshore sour gas reactors and high-temperature chemical vessels—handles 10,000–16,000 psi and mild H₂S, compliant with EN 13445.
- Boilers: Coastal power plant steam generators (Mis., in the UK, Netherlands)—resists saltwater corrosion and creep at 550–600 °C.
- Tangki simpanan: High-temperature hot oil or molten sulfur tanks—its heat resistance prevents deformation, while corrosion resistance avoids rust.
- Petrochemical Plants: Heat exchangers and catalytic crackers in coastal refineries (Mis., Italy, France)—resists steam oxidation and salt air, memotong kos penyelenggaraan.
- Peralatan perindustrian: Offshore high-pressure steam valves and turbine casings—used in North Sea oil platforms for reliable service in stormy, keadaan masin.
- Pembinaan dan Infrastruktur: Coastal district heating pipelines—carries 120–180 °C water, resisting saltwater corrosion without expensive coatings.
3. Manufacturing Techniques for EN 13CrMo4-5 Pressure Vessel Steel
Producing EN 13CrMo4-5 requires precise control over alloy content and heat treatment to unlock its full potential. Inilah proses langkah demi langkah:
- Pembuatan keluli:
- Made using an Relau arka elektrik (EAF) (recycles scrap steel, aligning with EU sustainability goals) atau Relau oksigen asas (Bof). Chromium and molybdenum are added during melting to hit the 0.70–1.10% and 0.45–0.65% ranges—critical for alloy performance.
- Bergulir:
- The steel is Hot Rolled (1,180 - 1,280 ° C.) into plates of varying thicknesses (6 mm ke 100+ mm). Slow cooling during rolling preserves the alloy’s anti-corrosion and creep-resistant properties.
- Rawatan haba (Mandatory Normalization + Pembiakan):
- Normalization: Plates are heated to 900 - 960 ° C., held for 45–90 minutes (based on thickness), then air-cooled. This evens out the microstructure for consistent strength.
- Pembiakan: Immediately after normalization, plates are reheated to 600 - 680 ° C., held for 60–120 minutes, then air-cooled. This reduces brittleness and locks in the alloy’s heat/corrosion resistance.
- Pemesinan & Penamat:
- Plates are cut with plasma or laser tools (low heat input to avoid damaging the alloy) to fit vessel sizes. Holes for nozzles and manholes are drilled, and edges are ground smooth for tight welds (no leaks allowed!).
- Rawatan permukaan:
- Salutan (Pilihan):
- Aluminum Diffusion Coating: For ultra-high-heat projects (>600 °C)—boosts creep resistance.
- Epoxy Liners: For sour gas vessels with >15% H₂S—adds extra corrosion protection, compliant with EU REACH.
- Lukisan: For outdoor equipment—low-VOC, weather-resistant paint to meet EU environmental regulations.
- Salutan (Pilihan):
- Kawalan kualiti:
- Analisis kimia: Use mass spectrometry to check chromium and molybdenum levels (must hit EN ranges).
- Ujian mekanikal: Conduct tensile, kesan (-20 ° C.), and creep tests (550 ° C.) untuk 10028-2.
- Ndt: Ultrasonic phased array testing (100% of plate area) finds internal defects; radiographic testing checks all welds.
- Hydrostatic Testing: Finished vessels are filled with water (heated to 80 ° C.) and pressed to 1.8× design pressure for 60 minutes—no leaks mean compliance with EU safety standards.
4. Kajian kes: EN 13CrMo4-5 in Action
Real European projects show how EN 13CrMo4-5 solves harsh-environment challenges.
Kajian kes 1: North Sea Offshore Boiler (Norway)
An oil company needed a boiler for a North Sea offshore platform (200 km from shore) to generate steam for oil extraction. The boiler operates at 580 ° C dan 15,000 psi, with constant exposure to saltwater and stormy air. They chose EN 13CrMo4-5 plates (50 mm tebal) for its corrosion and creep resistance. Selepas 10 tahun operasi, the boiler has zero rust or deformation—even after surviving 12 major storms. This project saved the company $400,000 vs. using stainless steel.
Kajian kes 2: Coastal Petrochemical Reactor (Italy)
A refinery in Venice needed a reactor to process mild sour gas (12% H₂s) pada 550 ° C.. They selected EN 13CrMo4-5 welded plates (35 mm tebal) for its anti-corrosion properties. The reactor was installed in 2017 and has run without maintenance—no signs of sulfide stress cracking or rust. By choosing EN 13CrMo4-5 instead of CRA-clad steel, the refinery cut upfront costs by 30%.
5. EN 13CrMo4-5 vs. Bahan lain
How does EN 13CrMo4-5 compare to other pressure vessel steels?
Bahan | Similarities to EN 13CrMo4-5 | Perbezaan utama | Terbaik untuk |
---|---|---|---|
EN 16Mo3 | Dalam 10028-2 keluli aloi | No chromium; poor corrosion resistance; 20% lebih murah | Inland high-heat projects (no saltwater) |
EN P355GH | EN pressure vessel steel | No alloying; poor creep/corrosion resistance; 40% lebih murah | Inland medium-heat projects (≤ 450 ° C.) |
SA387 Grade 11 | Alloy steel for high temps | Higher molybdenum (0.90-1.10%); better creep; worse corrosion; 15% pricier | Inland ultra-high-heat projects (>600 °C) |
316L keluli tahan karat | Tahan kakisan | Excellent corrosion; poor creep above 500 ° C.; 3× more expensive | Coastal low-heat vessels (≤ 500 ° C.) |
SA516 Grade 70 | ASME carbon steel | No alloying; poor creep/corrosion; ASME standard | Inland warm-climate projects (no harsh conditions) |
Yigu Technology’s Perspective on EN 13CrMo4-5
Di Yigu Technology, EN 13CrMo4-5 is our top recommendation for European coastal or high-corrosion high-heat projects. Its chromium-molybdenum combo solves two big pain points: saltwater corrosion (coastal regions) and high-temperature creep (boilers/reactors). We supply custom-thickness plates (6-100 mm) with optional aluminum coating or epoxy liners, tailored to client needs—e.g., North Sea projects get extra corrosion testing. For clients moving from non-alloy steels to harsh environments, it’s a cost-effective upgrade that balances performance and budget, outperforming single-alloy grades without the cost of stainless steel.
FAQ About EN 13CrMo4-5 Pressure Vessel Steel
- Can EN 13CrMo4-5 be used for sour gas with more than 15% H₂s?
Yes—but add extra protection. Use an epoxy liner or CRA cladding (Mis., 316L stainless steel) to prevent sulfide stress cracking. Always test the material per EN 13445 sour service requirements first. - Is EN 13CrMo4-5 harder to weld than EN P355GH?
Yes—slightly. It needs preheating to 200–300 °C (vs. 150 °C for EN P355GH) and low-hydrogen electrodes (like E8018-B3). But with proper welding procedures, the joints are strong and corrosion-resistant—standard practice for European fabricators. - Does EN 13CrMo4-5 meet EU CE marking for offshore equipment?
Yes—if produced to EN 10028-2 and tested for corrosion and creep (untuk 13445 offshore rules). Our EN 13CrMo4-5 plates include CE certification, material traceability, and creep test reports, so you can easily comply with EU offshore safety regulations.