EN 13CrMo4-5 Pressure Vessel Steel: Proprietà, Usi & Guida di produzione

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If you work on European high-temperature, high-corrosion pressure projects—like coastal power plant boilers, offshore petrochemical reactors, or sour gas pipelines—you need a steel that resists both creep and rust.EN 13CrMo4-5 pressure vessel steel is the premium solution: as a chromium-molybdenum alloy steel in EN 10028-2, its 0.70–1.10% chromium and 0.45–0.65% molybdenum deliver unbeatable heat stability and corrosion resistance, outperforming non-alloyed grades like EN P355GH. This guide breaks down its properties, usi del mondo reale, processo di produzione, and material comparisons to help you solve harsh-environment equipment challenges.

1. Material Properties of EN 13CrMo4-5 Pressure Vessel Steel

EN 13CrMo4-5’s performance comes from its dual-alloy design—chromium fights corrosion, while molybdenum resists creep—paired with strict heat treatment. Esploriamo in dettaglio le sue proprietà chiave.

1.1 Composizione chimica

EN 13CrMo4-5 adheres to EN 10028-2, with chromium and molybdenum as core elements for harsh conditions. Di seguito è la sua composizione tipica (per piastre ≤ 60 mm di spessore):

ElementoSimboloGamma di contenuti (%)Ruolo chiave
Carbonio (C)C0.12 - 0.18Enhances strength; kept low to preservesaldabilità (critical for thick-walled vessels)
Manganese (Mn)Mn0.40 - 0.70Aumentaresistenza alla trazione without reducing high-temperatureduttilità
Silicio (E)E0.10 - 0.35Aids deoxidation; stabilizes the steel structure at 500–600 °C
Fosforo (P)P≤ 0.025Minimized to prevent brittle fracture in cold or cyclic heat conditions
Zolfo (S)S≤ 0.015Strictly controlled to avoid weld defects (PER ESEMPIO., hot cracking) in coastal humidity
Cromo (Cr)Cr0.70 - 1.10Core anti-corrosion element; resists saltwater and steam oxidation
Molibdeno (Mo)Mo0.45 - 0.65Core creep-resistant element; prevents deformation at 500–600 °C
Nichel (In)In≤ 0.30Trace element; enhances low-temperatureLa tenacità dell'impatto (for winter boiler startup)
Vanadio (V)V≤ 0.03Trace element; refines grain structure to improvefatigue limit under cyclic heat
Rame (Cu)Cu≤ 0.30Trace element; adds extra atmospheric corrosion resistance for outdoor equipment

1.2 Proprietà fisiche

These traits make EN 13CrMo4-5 ideal for European harsh environments:

  • Densità: 7.87 g/cm³ (slightly higher than non-alloyed steels due to chromium/molybdenum; easy to calculate vessel weight)
  • Punto di fusione: 1,400 - 1,440 ° C. (2,552 - 2,624 ° f)—compatible with advanced welding processes (Tig, SEGA) for coastal projects
  • Conducibilità termica: 42.0 Con(M · k) A 20 ° C.; 36.5 Con(M · k) A 550 °C—ensures even heat distribution in boilers, reducing hot spots
  • Coefficiente di espansione termica: 11.7 × 10⁻⁶/° C. (20 - 550 ° C.)—minimizes damage from extreme heat cycles (PER ESEMPIO., 20 °C to 550 ° C.)
  • Proprietà magnetiche: Ferromagnetic—enables non-destructive testing (Ndt) like ultrasonic phased array to detect hidden defects in corrosion-prone areas.

1.3 Proprietà meccaniche

EN 13CrMo4-5’s normalization-and-tempering heat treatment ensures consistent performance in harsh conditions. Di seguito sono riportati valori tipici (per 10028-2):

ProprietàMeasurement MethodValore tipico (20 ° C.)Valore tipico (550 ° C.)EN Minimum Requirement (20 ° C.)
Durezza (Rockwell)HRB80 - 95 HRBN / AN / A (controllato per evitare la fragilità)
Durezza (Vickers)HV160 - 190 HVN / AN / A
Resistenza alla trazioneMPA480 - 620 MPA340 - 440 MPA480 MPA
Forza di snervamentoMPA290 - 410 MPA190 - 260 MPA290 MPA
Allungamento% (In 50 mm)22 - 28%N / A22%
La tenacità dell'impattoJ (A -20 ° C.)≥ 45 JN / A≥ 27 J
Fatigue LimitMPA (rotating beam)200 - 240 MPA150 - 190 MPAN / A (tested per heat cycles)

1.4 Altre proprietà

EN 13CrMo4-5’s traits solve key challenges for harsh-environment projects:

  • Saldabilità: Good—requires preheating to 200–300 °C (to avoid chromium-induced weld cracks) and low-hydrogen electrodes, but produces corrosion-resistant joints.
  • Formabilità: Moderate—can be bent into boiler shells or reactor curves (with controlled heating) without losing alloy benefits.
  • Resistenza alla corrosione: Excellent—resists saltwater (coastal Europe), steam oxidation (caldaie), and mild sour gas (fino a 15% H₂s); no extra coating needed for most coastal projects.
  • Duttilità: High—absorbs pressure spikes in high-heat reactors without fracturing, a critical safety feature.
  • Tenacità: Reliable—maintains strength at -20 ° C. (cold-region startup) E 600 ° C. (continuous operation), outperforming single-alloy steels like EN 16Mo3.

2. Applications of EN 13CrMo4-5 Pressure Vessel Steel

EN 13CrMo4-5’s dual-alloy 优势 makes it a staple in European harsh-environment equipment. Here are its key uses:

  • Boilers: Coastal power plant steam generators—operates at 550–600 °C, resisting saltwater corrosion from nearby oceans (PER ESEMPIO., Regno Unito, Netherlands).
  • Vasi a pressione: Offshore petrochemical reactors and sour gas storage vessels—handles 10,000–16,000 psi and mild H₂S, compliant with EN 13445.
  • Petrochemical Plants: Heat exchangers and catalytic crackers in coastal refineries—resists steam oxidation and salt air, reducing maintenance.
  • Serbatoi di stoccaggio: High-temperature hot oil or molten sulfur tanks—its heat resistance prevents deformation, while corrosion resistance avoids rust.
  • Attrezzatura industriale: Offshore high-pressure steam valves and turbine casings—used in North Sea oil platforms for reliable harsh-environment service.
  • Costruzione e infrastruttura: Coastal district heating pipelines—carries 120–180 °C water, resisting saltwater corrosion without extra coating.

3. Manufacturing Techniques for EN 13CrMo4-5 Pressure Vessel Steel

Producing EN 13CrMo4-5 requires precise control over chromium/molybdenum and heat treatment. Ecco il processo passo-passo:

  1. Making d'acciaio:
    • Made using an Fornace ad arco elettrico (Eaf) (aligns with EU sustainability goals) O Fornace di ossigeno di base (Bof). Cromo (0.70–1,10%) e molibdeno (0.45–0.65%) are added during melting to ensure alloy uniformity.
  2. Rotolando:
    • The steel is Laminato caldo (1,180 - 1,280 ° C.) into plates (6 mm a 100+ mm di spessore). Hot rolling uses slow cooling to preserve the alloy’s anti-corrosion and creep-resistant properties.
  3. Trattamento termico (Mandatory Normalization + Tempra):
    • Normalization: Plates heated to 900 - 960 ° C., held 45–90 minutes (based on thickness), then air-cooled—evens out microstructure.
    • Tempra: Reheated to 600 - 680 ° C., held 60–120 minutes, then air-cooled—reduces brittleness and locks in alloy benefits.
  4. Lavorazione & Finitura:
    • Plates cut with plasma/laser tools (low heat input to avoid alloy damage) to fit vessel sizes. Holes for nozzles are drilled, edges ground smooth for tight welds.
  5. Trattamento superficiale:
    • Rivestimento (Opzionale):
      • Aluminum Diffusion Coating: For ultra-high-heat boilers (>600 °C)—enhances creep resistance.
      • Epoxy Liners: For sour gas vessels (>15% H₂S)—adds extra corrosion protection, compliant with EU REACH.
    • Pittura: For outdoor equipment—low-VOC, weather-resistant paint to meet EU environmental standards.
  6. Controllo di qualità:
    • Analisi chimica: Mass spectrometry verifies chromium/molybdenum content (critical for alloy performance).
    • Test meccanici: Trazione, impatto (-20 ° C.), and creep tests (550 ° C.) per 10028-2.
    • Ndt: Ultrasonic phased array (100% plate area) and radiographic testing (welds) to detect defects.
    • Hydrostatic Testing: Vessels pressure-tested (1.8× design pressure, 80 °C water) per 60 minutes—no leaks = EU compliance.

4. Casi studio: EN 13CrMo4-5 in Action

Real European projects showcase EN 13CrMo4-5’s harsh-environment reliability.

Caso di studio 1: North Sea Offshore Boiler (Norway)

An oil company needed a boiler for a North Sea offshore platform (200 km from shore), Operando a 580 ° C e 15,000 psi. They chose EN 13CrMo4-5 plates (50 mm di spessore) per la sua resistenza alla corrosione (acqua salata) and creep resistance. Dopo 10 anni, the boiler has no rust or deformation—even in stormy, salt-rich air. This project saved $400,000 vs. using stainless steel.

Caso di studio 2: Coastal Petrochemical Reactor (Italy)

A refinery in Venice needed a reactor for mild sour gas (12% H₂s, 550 ° C.). EN 13CrMo4-5 welded plates (35 mm di spessore) were selected for their anti-corrosion and heat resistance. The reactor was installed in 2017 and has run without maintenance—its chromium content eliminated the need for expensive CRA cladding, cutting costs by 30%.

5. EN 13CrMo4-5 vs. Altri materiali

How does EN 13CrMo4-5 compare to other pressure vessel steels?

MaterialeSimilarities to EN 13CrMo4-5Differenze chiaveMeglio per
EN 16Mo3IN 10028-2 acciaio in legaNo chromium; poor corrosion resistance; più economicoInland high-heat projects (no saltwater)
EN P355GHEN pressure vessel steelNo alloying; poor creep/corrosion resistance; più economicoInland medium-heat projects (≤ 450 ° C.)
SA387 Grade 11Alloy steel for high tempsHigher molybdenum (0.90–1,10%); better creep; worse corrosion; 15% pricierInland ultra-high-heat projects (>600 °C)
316L in acciaio inossidabileResistente alla corrosioneExcellent corrosion; poor creep above 500 ° C.; 3× more expensiveCoastal low-heat vessels (≤ 500 ° C.)
SA516 Grade 70ASME carbon steelNo alloying; poor creep/corrosion; ASME standardInland warm-climate projects

Yigu Technology’s Perspective on EN 13CrMo4-5

Alla tecnologia Yigu, EN 13CrMo4-5 is our top pick for European coastal/high-corrosion high-heat projects. Its chromium-molybdenum combo solves two big pain points: corrosione (coastal salt) and creep (high temp). We supply custom-thickness plates (6–100 mm) with optional aluminum coating, tailored to regions (PER ESEMPIO., North Sea projects get extra corrosion testing). For clients moving from non-alloy steels to harsh environments, it’s a cost-effective upgrade—better performance than EN 16Mo3, cheaper than stainless steel.

FAQ About EN 13CrMo4-5 Pressure Vessel Steel

  1. Can EN 13CrMo4-5 be used for sour gas with >15% H₂S?
    Yes—with epoxy or CRA cladding. Its chromium resists mild H₂S, but for >15% concentrations, add a thin 316L cladding to prevent sulfide stress cracking. Test per EN 13445 sour service rules first.
  2. Is EN 13CrMo4-5 harder to weld than EN P355GH?
    Yes—needs preheating to 200–300 °C (vs. 150 °C for EN P355GH) and low-hydrogen electrodes (PER ESEMPIO., E8018-B3). But with proper training, welds are strong and corrosion-resistant—standard for European coastal projects.
  3. Does EN 13CrMo4-5 meet EU CE marking for offshore equipment?
    Yes—if produced to EN 10028-2 and tested for corrosion/creep (per 13445 offshore rules). Our plates include CE certification, Rapporti sui test di corrosione, and traceability—ready for North Sea or Mediterranean offshore use.
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